Simplified Analysis of Breakthrough Experiments
Автор: Rajamani Krishna
Загружено: 2022-10-21
Просмотров: 624
Описание:
There is currently an exponential growth in the development of MOFs for a wide variety of mixture separations of industrial interest. In most publications, the suitability of the MOF for any specified separation task is verified using transient breakthrough experiments. The comparison and screening of MOFs from breakthrough experimental data from different laboratories is challenging because of wide variation in the breakthrough apparatus dimensions, flow rates, mass of adsorbent samples. I address the question of the proper presentation of breakthrough data for easier comparisons of different MOFs. I also present a simplified analysis of breakthrough experiments that allows calculations of the productivities of purified product in the adsorption cycle.
For background consult my papers:
R. Krishna, Metrics for Evaluation and Screening of Metal-Organic Frameworks for Applications in Mixture Separations, ACS Omega 5 (2020) 16987−17004. https://doi.org/10.1021/acsomega.0c02218
Watch also Transient Breakthrough Simulations, Screening MOFs for Mixture Separations
on my YouTube channel / @rajamanikrishna250
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