Victor Albert, Quantum theory of molecular orientations, 2025.09.23
Автор: CodEx Seminar
Загружено: 2026-01-24
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Speaker: Victor Albert (University of Maryland and NIST)
Title: Quantum theory of molecular orientations
Date: 2025.09.23
Abstract:
We formulate a quantum phase space for molecular rotational and nuclear-spin states. Taking in molecular geometry and nuclear-spin data, we reproduce a molecule's admissible angular momentum states known from spectroscopy, introduce its angular position states using quantization theory, and develop a generalized Fourier transform converting between the two. Using induced representations of the rotation group, we classify molecules into three types — asymmetric, rotationally symmetric, and perrotationally symmetric — with the last type having no macroscopic analogue due to nuclear-spin statistics constraints. We identify molecular species whose position states house an internal pseudo-spin or “fiber” degree of freedom, and the fiber's Berry phase or matrix after adiabatic changes in position yields naturally robust operations, akin to braiding anyonic quasiparticles or realizing fault-tolerant quantum gates. We conjecture a necessary and sufficient condition on the Maurer-Cartan and Berry connections for such operations to exist on a general induced representation.
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