Sharpless Asymmetric Epoxidation Nantz , Carruthers CSIR NET GATE Chemistry

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Welcome to this advanced session on Sharpless Asymmetric Epoxidation, presented by Chiral Academy. This reaction is one of the most famous enantioselective oxidations in organic chemistry, and a frequently asked topic in CSIR NET, GATE Chemistry, IIT JAM, BARC, and Ph.D. entrance exams. In this lecture, we’ll break down the mechanism, reagent system, and stereochemical outcome of this Nobel Prize-winning reaction in a simple and conceptual manner.

In this video, you’ll learn:
Mechanism of Sharpless Asymmetric Epoxidation
Role of reagents: Ti(OiPr)₄, (+)/(–)-DET, and tert-butyl hydroperoxide
Mnemonic for predicting stereochemistry (Top face vs Bottom face attack)
Substrate scope and limitations
Stereochemical control and enantioselectivity
Applications in asymmetric synthesis and total synthesis examples
Tricks to remember absolute configuration and DET selection
Exam-focused MCQs and concept discussions

By the end of this session, you’ll clearly understand how to predict the configuration of Sharpless products, interpret mechanistic diagrams, and apply this reaction in synthesis-based questions.

✅ Perfect for:
CSIR NET and GATE Organic Chemistry aspirants
JAM, BARC, and M.Sc./Ph.D. entrance exam students
Anyone revising Asymmetric Synthesis and Stereoselective Reactions

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