𝟎𝟖 - 𝐂𝐨𝐦𝐩𝐥𝐞𝐱 𝐟𝐨𝐫𝐦𝐚𝐭𝐢𝐨𝐧 𝐭𝐢𝐭𝐫𝐚𝐭𝐢𝐨𝐧 & 𝐄𝐃𝐓𝐀 𝐜𝐨𝐦𝐩𝐥𝐞𝐱𝐨𝐦𝐞𝐭𝐫𝐢𝐜 𝐭𝐢𝐭𝐫𝐚𝐭𝐢𝐨𝐧
Автор: Mostafa El-Naggar
Загружено: 2025-05-24
Просмотров: 1013
Описание:
Mostafa El-Naggar (M.Sc)
Assistant Lecturer of Analytical Chemistry
Faculty of Science, Alexandria University, Egypt
This lecture provides a comprehensive academic overview of complex formation titrations, with a primary focus on EDTA complexometric titration, a widely used method in quantitative analysis of metal ions.
📘 Lecture Objectives:
• Define and explain the principles of complexometric titration
• Understand the role of chelating agents, particularly ethylenediaminetetraacetic acid (EDTA)
• Discuss metal-ligand complex stability.
• Explore the stoichiometry of complex formation reactions.
🔬 This lecture is suitable for:
• Undergraduate students in pharmaceutical sciences, chemistry, and environmental science
• Learners preparing for practical or theoretical examinations in analytical chemistry
• Anyone seeking a deeper understanding of quantitative metal ion analysis
This lecture covers the following points:
00:00 Introduction and Complex Formation Titration
09:08 ligand definition and Classification of the ligands
17:44 Titration curves in compleximetric titrations
19:38 Factors affecting the magnitude of the break in the titration curve
23:49 Titration of copper(II) against ammonia
30:53 Titration of copper(II) against polydentate ligand, trien.
32:45 Titration curve of Cu2+ against trien and NH3
35:10 The difference between complexometry and compleximetry
37:01 Titration involving unidentate ligands
(compleximetric titration)
39:03 Liebig’s method (Argentometric titration of cyanide)
46:00 Deniges Modification (Modification of Liebig’s method)
49:18 Mercurimetric Titration
52:24 Titrations with multidentate Ligands
53:59 Ethylene Diamine Tetra Acetic acid (EDTA) and its properties
01:11:36 Factors affecting stability of the metal-EDTA complexes
-Effect of pH
-Nature of the metal ion
01:16:18 EDTA Complexometric Titration Curves.
01:34:28 Factors affecting the shape of the titration curves in complexometric reactions (metal EDTA chelates)
1- The stability constant of the complex
2- The effect of pH
For Contact:
📍 Facebook personal account: / mostafa.elnaggar.14224
📍 Youtube channel: / @mostafanaggar-ie4jn
📍 Email address: [email protected]
📍 Mobile (Whatsapp): +20 10 12463029
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