Complete Organometallic Chemistry | CSIR-NET | GATE | IIT-JAM | MSc | BSc

Описание: 00:00:00 Initials
00:00:25 Introduction To Organometallic Compounds / Application / Hapticity
00:17:07 18 electron Rule / Neutral Atom Method/Oxidation State Method
00:37:53 Metal Corbonyl Complex-Structure, Stretching frequency etc
01:10:33 Reaction of carbonyl compound | Carbonylate ion | Metal Carbonyle Complex
01:28:52 Metal Cluster Compound /Calculation Of M-M Bond And Questions
01:44:06 High Nuclearity Carbonyl Clusters/Isolobal Analogy & Zintl ion
02:10:58 Metal Carbene Complex /Fischer Carbenes/Schrock Carbenes
02:31:27 bonding in fischer carbene | Stretching frequency
02:53:03 Oxidative addition/Reductive elimination/Migratory insertion/B-H elimination reactions
03:09:07 Oxidative Addition Reaction | Reductive Elemination Reaction | Detailed descriptions
03:46:05 Migratory Insertion Reaction | Beta-Hydrogen Elimination reaction detailed
04:09:42 Metallocene || Energy Level Diagram of Metallocene & Application
04:51:37 Ferrocene || Physical Properties & Chemical Reactions of Ferrocene
05:13:32 Wilkinson's Catalyst || Hydrogenation of alkenes || Organometallic Catalyst
05:36:45 Hydroformylation of alkenes or Oxo Process
05:49:57 Wacker Process || Wacker Oxidation || Catalytic Reaction || Conversion Of Alkenes to Acetaldehyde
06:12:23 Monsanto Acetic Acid Process & Cativa Process || Carbonylation Reaction || Catalyst


Topics Covered are:

Introduction to Organometallic Compounds, its application and hapticity of ligand, Describes 18 electron Rule of Organometallic Compound by two method, first by Neutral Atom Method and second by Oxidation State Method. why carbon atom donate lp's to metal, sigma donar and Pi accepter ligand, importance of Pi back bond,IR spectroscopy, Comparison of stretching frequency in different corbonyl compound etc. MO diagram of CO Molecule, Reaction of Carbonyl compound form two important product, one metal carbene complex and another carbonylate ion. Detailed information given about carbonylate ion, various type of question patterns generally asked in CSIR NET and Gate exam. Importance of Metal-Metal bond and 18 electron rule described, High Nuclearity Carbonyl Clusters/Isolobal Analogy & Zintl ion, metal carbene complex /Fischer Carbenes/schrock carbenes, bonding in fischer carbene | Stretching frequency, Oxidative addition/reductive elimination/Migratory insertion/B-H elimination reactions, ocene or sandwitch compounds, NMR spectral line of CP ligand, Energy Level Diagram of metallocene with examples and their applications, Magnetic Property of Metallocene etc, introduction of ferrocene, physical properties, NMR spectra & Chemical rections of ferrocene, Wilkinson's Catalyst including hydrogenation process by wilkinson's catalyst, features and selectivity, Mechanism and catalytic cycle. Some other catalyst used in hydrogenation process is covered, Hydroformylation process including introduction of Co/Rh corbonyle complex catalysts, mechanism of Hydroformylation explained by Catalytic Cycle. Disadvantage of Cobalt Corbonyle Catalyst, description of wacker process. Mechanism through Catalytic Cycle. Conversion Of Alkenes to Acetaldehyde in presence of PdCl4 and CuCl2. Organic Reaction question Practice of CSIR-NET exam, monsanto acetic acid Process & cativa process, carbonylation reaction


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List of Ligands with Hapticity: https://drive.google.com/open?id=15cL...