CHEM 2325 Module 24: Amide Structure
Автор: Brian Bocknack
Загружено: 2024-06-17
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An examination of the proton NMR spectrum of the primary amide butanamide shows that the two H atoms bonded to nitrogen are not equivalent. The reason is because an amide is a resonance hybrid, and the double bond character that exists in the C-N bond restricts rotation about this bond. The fact that an amide is a resonance hybrid also explains why there is trigonal planar geometry around N, and why the N atom is not nucleophilic or basic in its reactivity.
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