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ATROPISOMERISM AXIAL CHIRALITY EXAMPLES Biphenyls are connected by σ bond. Free Hindered rotation
Автор: KARANS CHEMWORLD
Загружено: 2024-10-03
Просмотров: 298
Описание:
ATROPISOMERISM or AXIAL CHIRALITY EXAMPLES Biphenyls are compounds where TWO PHENYL RINGS are connected by a central σ bond However, biphenyls with large substituents at the
ortho positions on either side of the central σ bond
experience restricted rotation along this bond due to
steric hindrance If the substituents are different, it will become a
CHIRAL molecule exhibiting a pair of enantiomers
called ATROPISOMERS obtained
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