NOMENCLATURE #14 || E Z naming system| CIP Rule || Geometric
Автор: CHEMISTRY TIPS & TRICKS WITH NAVEED AHMAD
Загружено: 2025-03-03
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Lecture #14: Nomenclature of Geometric Alkenes (E-Z System) | Cahn-Ingold-Prelog Rules
In this lecture, we have explained all the rules in detail for the E-Z nomenclature of alkenes using the Cahn-Ingold-Prelog (CIP) priority rules. This lecture is specially designed for MS, MSc, BS, MPhil, PhD, MDCAT, and other competitive exams.
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📌 Rules for E-Z Nomenclature of Alkenes
The E-Z system is used to name geometrical isomers of alkenes based on the Cahn-Ingold-Prelog (CIP) priority rules. The following steps explain how to assign the correct nomenclature:
1️⃣ Assign Priorities to Substituents
Each carbon in the C=C double bond has two groups attached to it.
Assign priorities based on the atomic number of the directly attached atom.
The higher atomic number gets higher priority.
If atoms directly attached are the same, move to the next atom along the chain.
2️⃣ Determine the Position of Higher Priority Groups
If the higher priority groups are on the same side of the double bond → Z (Zusammen)
If the higher priority groups are on the opposite side of the double bond → E (Entgegen)
3️⃣ Special Cases (Break Time, Dot Method, etc.)
Break Time Rule: If there is a tie in atomic numbers, compare the next bonded atoms until a difference is found.
Dot Method: Used when groups have the same atomic number; move along the chain until a difference is identified.
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📌 Examples of E-Z Nomenclature
Example 1:
CH₃-CH=CH-Cl
Cl has a higher atomic number than CH₃.
If higher priority groups are on the same side, the alkene is Z.
If on opposite sides, it is E.
Example 2:
Br-CH=CH-OH
Br (Atomic number = 35) and OH (Oxygen = 8).
Br has a higher priority than OH.
The naming follows the E-Z rule based on position.
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