Dive into the Fascinating World of Organolithium Reagents!
Автор: Mandeep Singh (ChemoSpecific)
Загружено: 2019-06-05
Просмотров: 2805
Описание:
In this video, we have discussed about the organolithium reagents along with questions from NET and GATE.
Video Chapter timeline:
0:00 Introduction
0:42 Generation of Organolithium (Li-Halogen Exchange)
8:41 4-Bromotoluene lithiation
10:21 Lithiation of Heterocycles
13:15 Generation of Organolithium (Li-Metal Exchange)
16:59 Generation of Organolithium (Li-Hydrogen Exchange)
19:53 Role of TMEDA/HMPA/DMPU/Crown Ether in Enolate Chemistry
22:45 Directed ortho-Lithiation
25:48 Directed ortho-Lithiation (contd.)
29:18 Loads of Examples of Directed ortho-Lithiation
42:56 Very Important Example
44:50 Lithiation of Immine
47:46 Lithiation of Immine bearing Chiral Auxiallry
51:15 Lithiation of N-Boc piperidine
52:46 Examples of Lithiation using s-BuLi/(-)-Sparteine
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