Radical Reactions||Radical Addition Reaction||Baldwin Rule||Lots of Poroblems||CSIR-NET GATE||Tricks

Описание: In this lecture, we are going to discuss about the radical addition reaction by using Bu3SnH(Tributyltin hydride) and AIBN(Azobisisobutyronitrile) by utilizing Baldwin's Rule. According to Baldwin rule:
The relative rates of ring closures of these various types. These terms are not meant to describe the absolute probability that a reaction will or will not take place, rather they are used in a relative sense. A reaction that is disfavoured (slow) does not have a rate that is able to compete effectively with an alternative reaction that is favoured (fast). However, the disfavoured product may be observed, if no alternate reactions are more favoured.

The rules classify ring closures in three ways:

1/ The number of atoms in the newly formed ring.
2/ Into exo and endo ring closures, depending whether the bond broken during the ring closure is inside (endo) or outside (exo) the ring that is being formed.
3/ Into tet, trig and dig geometry of the atom being attacked, depending on whether this electrophilic carbon is tetrahedral (sp3 hybridised), trigonal (sp2 hybridised) or digonal (sp hybridised).


(Reagent Series)
.............................................................................................................................
You can follow my FB Page @Chem Explore for more job update (more than 500 chemistry questions are available free!!!!!)
  / chem-explore-102765491463562  
..............................................................................................................
My web-page link:
https://sumanchiitk.wixsite.com/suman...
....................................................................................~~~~~~~~~~~~~~~

Recommendate Video:
Full Reagent Series Playlist:    • PCC Oxidation of Alcohols into Aldehydes a...  

C-C Cross Coupling Reaction Playlist:    • C-C Cross Coupling Reaction  

Organic Spectroscopy Full Series:
   • NMR Spectroscopy - A Basic Introduction ||...  

Organic Photochemistry Playlist link:    • Barton Reaction | Mechanism | Previous Yea...  

Full Heterocyclic Series link:
   • An Introduction, Properties & Reactions of...  

Full Pericyclic Reaction Series link:
   • Pericyclic Reactions || Basic Introduction...  

Organic name reaction playlist:
   • Birch Reduction of Aromatic Compounds with...  

Stereochemistry series playlist:
   • Stereochemistry Part-1|| Chiralcentre| Wed...  
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

Thanks for watching my videos. Kindly subscribe to Chem explore and share with your friends.
Keep Sharing, Keep Supporting!!!
Suman Bhowmick

................................................................................................................
#radical_reaction #radical_addition_reaction #Baldwin_rule #chemexplore #Bu3SnH_AIBN_reagent_reaction #organic_chemistry #organic_synthesis #Bu3SnH #AIBN#free_radical_addition_reaction #Bu3SnH_AIBN_radical_reaction #free_radical_reaction #radical_addition_reaction_mechanism #reagent_series #chemical_science #radical_addition_reaction_problems_in_csirnet_gate #csirnet_chemistry_radical_addition_reaction_problem #radical_addition_reaction_problems_in_csirnet_gate #csirnet_chemistry_radical_based_reagent_problem #gate_chemistry_radical_addition_based_reagent_problem #csir_net #DU #BHU #MSc. (in Hindi & English)


Disclaimer

Copyright Disclaimer Under Section 107 of the Copyright Act 1976, allowance is made for "fair use" for purposes such as comment, news reporting, teaching, scholarship, and research. Fair use is a use permitted by copyright statute that might otherwise be infringing. Non-profit, educational or personal use tips the balance in favor of fair use.

The information provided on this channel is a public service with the understanding that Chem Explore CSIR-NET GATE IIT-JAM IIT-JEE makes no warranties, either expressed or implied, related to completeness, accuracy, reliability or suitability of the information. The channel disclaims liability for errors and omissions that may have crept in its content.